Detailed explanations are given for the carbonates because the diagrams are easier to draw, and their equations are also easier. The carbonates and nitrates of group 2 elements carbonates become more thermally stable as you go down the Group. The activation energy for decomposition determined by isothe Brown nitrogen dioxide gas is given off together with oxygen. The nitrates are white solids, and the oxides produced are also white solids. If you calculate the enthalpy changes for the decomposition of the various carbonates, you find that all the changes are quite strongly endothermic. Since both 2-methyl-2-butanol nitrate and 2-methyl-2-propanol nitrate exhibited low thermal stability, they were not distilled from the reaction solvent diethyl ether. Due to the large size of the sulphate anion there is little difference betw… For the sake of argument, suppose that the carbonate ion radius was 0.3 nm. 1. This is because the cation size increases down the Group, this reduces the charge density and polarising power of cation. That's entirely what you would expect as the carbonates become more thermally stable. If you calculate the enthalpy changes for the decomposition of the various carbonates, you find that all the changes are quite strongly endothermic. That's entirely what you would expect as the carbonates become more thermally stable. The larger compounds further down require more heat than the lighter compounds in order to decompose. But they don't fall at the same rate. The argument is exactly the same here. The present paper deals with the thermal stability of hydroxidenitrate systems of alkali and alkaline-earth metals. All the nitrates in this Group undergo thermal decomposition to give the metal oxide, nitrogen dioxide and oxygen. You need to find out which of these your examiners are likely to expect from you so that you don't get involved in more difficult things than you actually need. If "X" represents any one of the elements: As you go down the Group, the carbonates have to be heated more strongly before they will decompose. Questions on the thermal stability of the Group 2 carbonates and nitrates. Don't waste your time looking at it. In the oxides, when you go from magnesium oxide to calcium oxide, for example, the inter-ionic distance increases from 0.205 nm (0.140 + 0.065) to 0.239 nm (0.140 + 0.099) – an increase of about 17%. The lattice enthalpies of both carbonates and oxides fall as you go down the Group because the positive ions are getting bigger. It explains how the thermal stability of the compounds changes down the group. The nitrate ion is bigger than an oxide ion, and so its radius tends to dominate the inter-ionic distance. In this video we want to explain the trends that we observe for thermal decomposition temperatures for Group 2 Metal Salts. Remember that the reaction we are talking about is: You can see that the reactions become more endothermic as you go down the Group. The next diagram shows the delocalised electrons. The oxide lattice enthalpy falls faster than the carbonate one. Note: If you are interested, you could follow these links to benzene or to organic acids. This page offers two different ways of looking at the problem. Drawing diagrams to show this happening is much more difficult because the process has interactions involving more than one nitrate ion. If you aren't familiar with Hess's Law cycles (or with Born-Haber cycles) and with lattice enthalpies (lattice energies), you aren't going to understand the next bit. THERMAL STABILITY OF THE GROUP 2 CARBONATES AND NITRATES This page looks at the effect of heat on the carbonates and nitrates of the Group 2 elements - beryllium, magnesium, calcium, strontium and barium. The thermal stability of strontium and barium hydroxide—nitrate systems increases at some peculiar compositions. Brown nitrogen dioxide gas is given off together with oxygen. Lattice enthalpy: the heat evolved when 1 mole of crystal is formed from its gaseous ions. The increasing thermal stability of Group 2 metal Unfortunately, in real carbonate ions all the bonds are identical, and the charges are spread out over the whole ion - although concentrated on the oxygen atoms. This page looks at the effect of heat on the carbonates and nitrates of the Group 2 elements – beryllium, magnesium, calcium, strontium and barium. All the carbonates in this group undergo thermal decomposition to the metal oxide and carbon dioxide gas. Which of these statements is correct? In the oxides, when you go from magnesium oxide to calcium oxide, for example, the inter-ionic distance increases from 0.205 nm (0.140 + 0.065) to 0.239 nm (0.140 + 0.099) - an increase of about 17%. What factors affect this trend? The Effect of Heat on the Group 2 Nitrates All the nitrates in this Group undergo thermal decomposition to give the metal oxide, nitrogen dioxide and oxygen. The decomposition temperature of - and -substituted derivatives is found to be linearly related to the Hammett substituent constant σ. If the attractions are large, then a lot of energy will have to be used to separate the ions - the lattice enthalpy will be large. The lattice enthalpies of both carbonates and oxides fall as you go down the Group because the positive ions are getting bigger. The effect of heat on the Group 2 nitrates. You need to find out which of these your examiners are likely to expect from you so that you don't get involved in more difficult things than you actually need. The explanation for change in thermal stability is the same as for carbonates Magnesium nitrate decomposes the easiest because the Mg 2+ ion is smallest and has the greater charge density. if you constructed a cycle like that further up the page, the same arguments would apply. It describes and explains how the thermal stability of the compounds changes as you go down the Group. Again, if "X" represents any one of the elements: As you go down the Group, the nitrates also have to be heated more strongly before they will decompose. Lithium carbonate and Group 2 nitrates become more thermally stable produced are white... Nitrates also become more stable to heat the carbonate to the main page dioxide... Mark schemes to use the BACK BUTTON on your browser to come BACK here afterwards, with barium sulphate insoluble... Give the metal oxide, © Jim Clark 2002 ( modified February )! Ca n't use real figures the Hammett substituent constant σ your browser to come BACK here.... 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